Removal of Organic Dye in Wastewater Using Polyethersulfone Hollow Fiber Membrane

Authors

  • Asyrine Abdullah Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Prakash Peechmani Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Mohd Hafiz Dzarfan Othman Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Mohd Hafiz Puteh ᵃAdvanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia ᵇDepartment of Environmental Engineering, School of Civil Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Juhana Jaafar Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Muklis A. Rahman Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Ahmad Fauzi Ismail Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/amst.v26n2.238

Keywords:

Polyethersulfone (PES), Polvinylpyrrolidone (PVP), dye rejection, Direct Red 80

Abstract

In this study, polyethersulfone (PES) hollow fiber membranes (HFM) were fabricated with different weight percentage (wt. %) of polymer at 16 wt. %, 18 wt. % and 20 wt. %, in order to study the impact of polymer weight percentages on membrane properties and its dye rejection performance. Microfiltration HFM were fabricated by using the laboratory dry-wet spinning method. In order to improve the pore structure of the polymer membrane, 3 wt. % of   (PVP) of 8000 M.W. was added in the dope solution. All the fabricated PES hollow fiber membranes were characterized using the Scanning Electron Microscopy (SEM), Atomic Force Microscope (AFM), Fourier Transform Infrared Spectroscopy (FTIR) and the contact angle. The HFM’s performance was evaluated in terms of dye rejection, by using Direct Red 80 dye as substitute of organic dye in wastewater. The results  ed that the membrane with higher weight percentage of PES polymer (20 % PES) had thicker separation layer, smoother membrane surface and uniform like pore structures. The membrane with the higher weight percentage of polymer (20% PES) had higher dye rejection percentage (67.33%) and higher permeate flux (10.024 L/m2h) compared to 16 wt. % and 18 wt. %. The results of this study revealed that the weight percentage of polymer in the membrane did affect the membrane properties and its performance.

 

 

 

References

Lellis, B., Fávaro-Polonio, C. Z., Pamphile, J. A., Polonio, J. C. 2019. Effects of Textile Dyes on Health and the Environment and Bioremediation Potential of Living Organisms. Biotechnology Research and Innovation. (2): 275-290.

Shen, X., Zhang, T., Xu, P., Zhang, L., Liu, J., Chen, Z. 2017. Growth of C3N4 Nanosheets on Carbon-fiber Cloth as Flexible and Macroscale Filter-Membrane-shaped Photocatalyst for Degrading the Flowing Wastewater. Applied Catalysis B: Environmental. 19: 425-431.

Ali, M. E. A., Atta, A. H., Medhat, M., Shahat, A., Mohamed, S. K. 2022. Effective Removal of Methyl Blue and Crystal Violet Dyes Using Improved Polysulfone / Zif-8 Nanocomposite Ultrafiltration Membrane. Biointerface Research in Applied Chemistry. 12(6): 7942-7956.

Martínez-Huitle, C. A., Brillas, E. 2009. Decontamination of Wastewaters Containing Synthetic Organic Dyes by Electrochemical Methods: A General Review. Applied Catalysis B: Environmental. 105-145.

Kant, R. 2012. Textile Dyeing Industry an Environmental Hazard. Natural Science. 04(01): 22-26.

Zheng, J., Zhao, R., Uliana, A. A., Liu, Y., de Donnea, D., Zhang, X., Xu, D., Gao, Q., Jin, P., Liu, Y., Volodine, A., Zhu, J., van der Bruggen, B. 2022. Separation of Textile Wastewater Using a Highly Permeable Resveratrol-based Loose Nanofiltration Membrane with Excellent Anti-fouling Performance. Chemical Engineering Journal. 434.

Bao, X., Wang, F., Liu, Q., Yu, F., Yang, Y. 2022. Controlled Aggregation of Phytic Acid Metal Complex on Polysulfone Ultrafiltration Membrane toward Simultaneous Rejection of Highly Emulsified Oils and Dyes. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 641.

Qiao, L., Ye, H., Xin, Q., Huang, L., Zhang, Y., Li, H. 2022. An Adsorptive Sulfonated Polyethersulfone/Functionalized Graphene Ultrafiltration Membrane for Hardness Removal. Separation and Purification Technology. 287.

Munir Cheryan. 1998. Ultrafiltration and Microfiltration: Handbook. CRC Press. 1-75.

Poolachira, S.; Velmurugan, S. 2022. Efficient Removal of Lead Ions from Aqueous Solution by Graphene Oxide Modified Polyethersulfone Adsorptive Mixed Matrix Membrane. Environmental Research. 210.

Lin, Z., Liu, Y., Zhang, Z., Yao, J. 2022. Preparation and Characterization of OH/SiO2-TiO2/PES Composite Hollow Fiber Membrane Using Gas-Liquid Membrane Contactor for CO2/CH4 Separation. Separation and Purification Technology. 288.

Ma, D., Zou, X., Zhao, Z., Zhou, J., Li, S., Yin, H., Wang, J. 2022. Hydrophilic PAA-g-MWCNT/TiO2@PES Nano-Matrix Composite Membranes: Anti-Fouling, Antibacterial and Photocatalytic. European Polymer Journal. 168: 111006.

Rabiee, H., Seyedi, S. M., Rabiei, H., Alvandifar, N. 2016. Improvements in Permeation and Fouling Resistance of PVC Ultrafiltration Membranes via Addition of Tetronic-1107 and Triton X-100 as Two Non-Ionic and Hydrophilic Surfactants. Water Science and Technology. 74(6): 1469-1483.

Ulbricht, M. 2006. Advanced Functional Polymer Membranes. Polymer. Elsevier BV. 2217-2262.

Xu, Z.-L., Chung, T.-S., Huang, Y. U. 1999. Effect of Polyvinylpyrrolidone Molecular Weights on Morphology, Oil/Water Separation, Mechanical and Thermal Properties of Polyetherimide/Polyvinylpyrrolidone Hollow Fiber Membranes. Applied Polymer. 74(9): 2220-2233.

Febriasari, A., Ananto, A. H., Kartohardjono, S. 2021. Polysulfone Filtration Membranes with Polyvinilpirrolidone (PVP) Additive for Batik Wastewater Treatment. J. Applied Membrane Science & Technology. 25(1): 1-9.

Fadaly, N. S., Aziz, F. 2020. Preparation and Characterization of Mixed Matrix Membrane Based on Polysulfone (PSF) and Lanthanum Orthoferrite (LaFeO3) for Gas Separation. Journal of Applied Membrane Science & Technology. 24(1).

Jin, J., Du, X., Yu, J., Qin, S., He, M., Zhang, K., Chen, G. 2020. High Performance Nanofiltration Membrane Based on SMA-PEI Cross-linked Coating for Dye/Salt Separation. Journal of Membrane Science. 611.

Ahmad, A. L., Abdulkarim, A. A., Mohd Shafie, Z. M. H., Ooi, B. S. 2017. Fouling Evaluation of PES/ZnO Mixed Matrix Hollow Fiber Membrane. Desalination. 403: 53-63.

Cheng, J., Shi, W., Zhang, L., Zhang, R. 2017. A Novel Polyester Composite Nanofiltration Membrane Formed by Interfacial Polymerization of Pentaerythritol (PE) and Trimesoyl Chloride (TMC). Applied Surface Science. 416: 152-159.

Barzin, J., Feng, C., Khulbe, K. C., Matsuura, T., Madaeni, S. S., Mirzadeh, H. 2004. Characterization of Polyethersulfone Hemodialysis Membrane by Ultrafiltration and Atomic Force Microscopy. Journal of Membrane Science. 237(1-2): 77-85.

Alpatova, A., Kim, E. S., Sun, X., Hwang, G., Liu, Y., Gamal El-Din, M. 2013. Fabrication of Porous Polymeric Nanocomposite Membranes with Enhanced Anti-fouling Properties: Effect of Casting Composition. Journal of Membrane Science. 444: 449-460.

Li, P., Thankamony, R. L., Li, X., Li, Z., Liu, X., Lai, Z. 2021. Nanoporous Polyethersulfone Membranes Prepared by Mixed Solvent Phase Separation Method for Protein Separation. Journal of Membrane Science. 635.

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Published

2022-07-25

How to Cite

Abdullah, A., Peechmani, P., Dzarfan Othman, M. H., Puteh, M. H., Jaafar, J., A. Rahman, M. ., & Ismail, A. F. (2022). Removal of Organic Dye in Wastewater Using Polyethersulfone Hollow Fiber Membrane . Journal of Applied Membrane Science & Technology, 26(2), 29–42. https://doi.org/10.11113/amst.v26n2.238

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