The Effect of MDEA/AMP and Span-80 in Water-in-Oil (W/O) Emulsion for Carbon Dioxide Absorption
DOI:
https://doi.org/10.11113/amst.v26n2.236Keywords:
Absorption, Amine, Carbon Dioxide, Liquid Emulsion, StabilityAbstract
Emulsion liquid membrane (ELM) has been widely studied as an alternative method for amine absorption technology in the removal of acid gases such as carbon dioxide (CO2) and hydrogen sulphide (H2S). However, searching for stable ELM formulation with an enhanced CO2 absorption remains as challenge. Therefore, in this study, the aqueous solution containing a mixture of methyl diethanolamine (MDEA) and 2-amino-2-methyl-1-propanol (AMP) in sodium hydroxide (NaOH) solution was introduced as a dispersed phase, kerosene as continuous phase and Span-80 acts as a surfactant for the formation of water-in-oil (W/O) emulsion. In this study, the dispersed phase consists of 8% v/v MDEA and 4% v/v AMP and the continuous phase which contains 6% v/v Span-80 produced a stable emulsion and exhibited 65.2% of CO2 removal. This study indicates that the introduction of blended amine able to produce stable emulsion with an enhanced CO2 removal.
References
H. R. Mortaheb, A. A. Nozaeim, M. Mafi, and B. Mokhtarani. 2012. Absorption of Carbon Dioxide in Emulsion Of Aqueous Monoethanolamine/Diethanolamine Solutions in Kerosene/N-Heptane. Chemical Engineeering Science. 82: 44-51.
B. P. Mandal and S. S. Bandyopadhyay. 2006. Absorption of Carbon Dioxide into Aqueous Blends of 2-amino-2-methyl-1-propanol and monoethanolamine. Chemical Engineering Science. 61: 5440- 5447.
M. K. Aroua, M. Z. Haji-Sulaiman, and K. Ramasamy. 2002. Modelling of Carbon Dioxide Absorption in Aqueous Solutions of AMP and MDEA and Their Blends using Aspenplus. Separation and Purification Technology. 29: 153-162.
J. Xiao, C.W. Li, and M. H. Li. 2000. Kinetics of Absorption of Carbon Dioxide into Aqueous Solutions of 2-Amino-2-Methyl-1-Propanol Monoethanolamine. Chemical Engineering Science. 55: 161-175.
P. Gunasekaran, A. Veawab, and A. Aroonwilas. 2013. Corrosivity of Single and Blended Amines in CO2 Capture Process. Energy Procedia. 37: 2094-2099.
A. K. Chakravarti, S. B. Chowdhury and D. C. Mukherjee. 2000. Liquid Membrane Multiple Emulsion Process of Separation of Copper (II) from Waste Waters. Colloids Surface A. 166: 7-25.
V. S. Kislik. 2010. Liquid Membranes Principle and Application in Chemical Separations and Wastewater Treatment. Elsevier, Jerusalem.
A. L. Ahmad, A. Kusumastuti, C. J. C. Derek, B. S. Ooi. 2011. Emulsion Liquid Membrane for Heavy Metal Removal: An Overview on Emulsion Stabilization and Destabilization. Chemical Engineering Journal. 171: 870-882.
S. W. Park, B. S. Choi, S. S. Kim, and J. W. Lee. 2007. Chemical Absorption of Carbon Dioxide into Aqueous Colloidal Silica Solution Containing Monoethanolamine. Journal of Industrial Engineering Chemistry. 13(1): 133-142.
G. Lv., W. Fumin, C. Wangfeng, Z. Xubin. 2014. Characterization of the Addition of Lipophilic Span 80 to the Hydrophilic Tween 80-stabilized Emulsions. Colloids and Surfaces A: Physicochem. Eng. Aspects. 447: 8-13.
A. Kargari, T. Kaghazchi, and M. Soleimani. 2003. Role of Emulsifier in the Extraction of Gold (iii) Ions from Aqueous Solutions Using the Emulsion Liquid Membrane Technique. Desalination. 162: 237-247.
M. Chakraborty, C. Bhattacharya, and S. Datta. 2010. Emulsion Liquid Membranes: Definitions and Classification, Theories, Module Design, Applications, New Directions and Perspective. Elsevier, India. 141-197.
I. Bhatti, K. Qureshi, K. S. N. Kamarudin, A. Ahmed Bazmi, A. W. Bhutto, F. Ahmad, and M. Lee. 2016. Innovative Method to Prepare a Stable Emulsion Liquid Membrane for High CO2 Absorption and Its Performance Evaluation for a Natural Gas Feed in a Rotating Disk Contactor. Journal of Natural Gas Science and Engineeering. 34: 716-732.
M. Sarbar, and K. M. Al-Jaziri. 1995. Laboratory Investigation of Factors Affecting the Formation and Stability of Tight Oil-in-water Emulsions in Produced Fluids. OAPEC Conference on New Technology. 1: 261-268.
C. J. Morales, U. Riebel, N. M. Guzmán, and M. Guerra. 2011. Formulation of Water in Paraffin Emulsions. Latin American Applied Research. 41: 105-112.
I. Bhatti. 2011. Separation of Carbon Dioxide from Natural Gas by Emulsion Liquid Membrane in Rotating Disc Contactor. Thesis (PhD). Universiti Teknologi Malaysia, Malaysia.
N. Dolmat. 2012. Carbon Dioxide Removal Using Methyldiethanolamine and Piperazine in Emulsion Liquid Membrane. Thesis (Master). Universiti Teknologi Malaysia, Malaysia.
A. Mohamed, S. I. Okoye, J. Salisu. 2016. Effect of Dispersed Phase Viscosity of Emulsions Produced by a Rotor Stator Homogenizer. International Journal Science Basic Applied Research. 25(2): 256-267.
S. Shi, Y. Wang, Y. Liu, L. Wang. 2018. A New Method for Calculating the Viscosity of W/O and O/W Emulsion. Journal of Petroleum Science and Engineering. 171: 928-937.
T. Sema, A. Naami, K. Fu, M. Edali, H. Liu, H. Shi, Z. Liang, R. Idem, P. Tontiwachwuthikul. 2012. Comprehensive Mass Transfer and Reaction Kinetics Studies of CO2 Absorption into Aqueous Solutions of Blended mdea/mea. Chemical Engineering Journal. 209: 501-512.
A. Ali Khan, G. N. Halder, A. K. Saha. 2016. Comparing CO2 Removal Characteristics of Aqueous Solutions of Monoethanolamine, 2-amino-2-methyl-1-propanol, Methyldietahnolamine and Piperazine through Absorption Process. International Journal of Greenhouse Gas Control. 50: 179-189.
J. T. Baker, and Jr., L. H. 1994. Allen Assessment of the Impact of Rising Carbon Dioxide and Other Potential Climate Changes on Vegetation. Environmental Pollution. 83: 223-235.
H. Rodriguez, L. Mello, W. Salvagini, J. L. de Paiva. 2011. Absorption of Carbon Dioxide into Aqueous Solution of Alkanolamine in a Wetted Wall Column with Film Promoter. Chemical Engineering Transactions. 25: 51-56.
A. Samantha, and S. S. Bandyopadhyay. 2009. Absorption of Carbon Dioxide into Aqueous Solutions of Piperazine Activated 2-amino-2-methyl-1-propanol. Chemical Engineering Science. 64: 1185-1194.
D. J. McClements and S. M. Jafari. 2018. Improving Emulsion Formation, Stability and Performance using Mixed Emulsifiers: A Review. Advances in Colloid and Interface Science. 251: 55-79.
N. N. Li. 1998. Separating Hydrocarbons with Emulsion Liquid Membranes. US Patent No. 3,410,794.119. Exxon Research and Engineering Company; U.S. Patent.
A. H. P. Skelland, and X. Meng. 1999. Non-Newtonian Conversion Solves Problems of Stability, Permeability, and Swelling in Emulsion Liquid Membranes. Journal of Membrane Science. 1: 158.
C. Ansel, L. V. Allen, and N. G. 2005. Popovich, Disperse Systems – Pharmaceutical Dosage Forms & Drug Delivery Systems. 8th edition. Lippincot Williams and Wiklkins, Philadelphia. 387-389.
Downloads
Published
How to Cite
Issue
Section
License
Copyright of articles that appear in Journal of Applied Membrane Science & Technology belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.