Elimination of an Endocrine Disruptive Chemical by PSf/TiO2 hybrid Membranes via Membrane Rejection and Photocatalytic Oxidation

Authors

  • V. S. Babu Center for Nano and Material Sciences, Jain University, Jakkasandra, Kanakapura Taluk, Ramanagar District–562112, India
  • M. S. Jyothi Center for Nano and Material Sciences, Jain University, Jakkasandra, Kanakapura Taluk, Ramanagar District–562112, India
  • Laveena P. D’Souza Center for Nano and Material Sciences, Jain University, Jakkasandra, Kanakapura Taluk, Ramanagar District–562112, India
  • R. Shwetharani Center for Nano and Material Sciences, Jain University, Jakkasandra, Kanakapura Taluk, Ramanagar District–562112, India
  • Mahesh Padaki Center for Nano and Material Sciences, Jain University, Jakkasandra, Kanakapura Taluk, Ramanagar District–562112, India
  • R. Geetha Balakrishna Center for Nano and Material Sciences, Jain University, Jakkasandra, Kanakapura Taluk, Ramanagar District–562112, India

DOI:

https://doi.org/10.11113/amst.v19i1.20

Abstract

This study reports removal of oxybenzone from TiO2 nanoparticles and those incorporated mixed matrix membrane. Polysulfone and TiO2 nanoparticles mixed matrix membrane were prepared by Diffusion Induced Phase Separation (DIPS) method. The TiO2 nanoparticles and membranes were characterized by XRD, SEM, TEM, Raman spectroscopy and FESEM techniques; analysis depicts 100% anatase with spherical crystallite size averaging around 17 nm. The mixed matrix membranes were used for bifunctional application, physical separation and organic degradation. The membranes were subjected to pure water flux and contact angle measurements, the influence of TiO2 were to increase the hydrophilicity of the membrane, the performance of the membrane in physical separation showed prominent results by removing oxybenzone up to 95% where as in organic degradation membrane showed 80% of degradation. The efficiency of the membrane in degradation was more prominent as compared to bare TiO2 nanoparticles. The TiO2 nanoparticles show around 70% of degradation, whereas, the bifunctionality of the membranes showed more prominence in removal of complete oxybenzone.

References

Johnson. A. C., Sumpter. J. P. 2001. Removal Of Endocrine-Disrupting Chemicals In Activated Sludge Treatment Works. Environmental Science and Technology. 35 (24): 4697–4703.

Schlumpf, M. B. Cotton. M. C. Haller. V. Steinmann. B. Lichtensteiger. W. 2001. In Vitro And In Vivo Estrogenicity Of UV Screens. Environmental Health Perspectives. 109(3): 239–244.

Kasichayanula, S. House. J. D. Wang. T. Gu. X. 2007. Percutaneous Characterization Of The Insect Repellent DEET And The Sunscreen Oxybenzone From Topical Skin Application. Toxicology and Applied Pharmacology. 223(2): 187–194.

Burnett, M. E. Wang. S. Q. 2011. Current Sunscreen Controversies: A Critical Review. Photodermatology, Photoimmunology & Photomedicine. 27(2): 58–67.

Shaach, N. A. Griffin, P. M. Andemichael. G. 1990. Interpretation And Evaluation: Spectroscopic Data Of Sunscreens. Sunscreens (Cosmetics). 37–541

Runger, T. M. Lehman, P. Matthies. C. Schauder. S. Munzberger. C. 1995. Recommendation Of A Photo Patch Test Standard Series By The German-Language Working Group. Photopatch-Test, Hautarzt. 46: 240–243.

Sundaram, C., Koster, W., Schallreuter, K. U. 1990. The Effect Of UV Radiation And Sun Blockers On Free Radical Defence In Human And Guinea Pig Epidermis. Anti Dermatol Res. 282: 326–331.

Nick, Serpone, Daniele Dondi. Angelo. Albini. 2007. Inorganic And Organic UV Filters: Their Role And Efficacy In Sunscreens And Suncare Products. Inorganica Chimica Acta. 360: 794–802.

Khodja, A. A. Sehili. T. Pilichowski, J. F. Boule. P. 2001. Photocatalytic Degradation of 2-phenylphenol on TiO2 and ZnO in Aqueous Suspensions. J. Photochem. Photobiol. A: Chem. 141: 231–239.

Chen, D., Ray, A. K. 1998. Photodegradation Kinetics Of 4-nitrophenol In TiO2 Suspension. Water Res. 32: 3223–3234.

Gomes da Silva, C. Faria, J. L. 2003. Photochemical And Photocatalytic Degradation Of An Azo Dye In Aqueous Solution By UV Irradiation. J. Photochem. Photobiol. A: Chem. 155: 133–143.

Kusvuran, E., Gulnaz, O., Irmak. S., Atanur, O. M., Yavuz, H. I., Erbatur, O. 2004. Comparison Of Several Advanced Oxidation Process For The Decolorization Of Reactive Red 120 Azo Dye In Aqueous Solution. J. Hazardous Mater. 109: 85–93

Fox, M. A., Dulay, M. T. 1993. Heterogeneous Photocatalysis. Chem. Rev. 93: 341–357.

Galindo, C., Jacques, P., Kalt, A. 2000. Photochemical And Photocatalytic Degradation Of An Indigoid Dye: A Case Study Of Acid Blue 74 (AB74). J. Photochem. Photobiol. A: Chem. 141: 47–56.

Turchi, C. S., Ollis, D. F. 1990. Photocatalytic Degradation Of Organic Water Contaminants: Mechanism Involving Hydroxyl Radical Attack. J. Catal. 122: 178–192.

Irmak, S., Kusvuran, E., Erbatur. O. 2004. Degradation Of 4-chloro-2-methylphenol In Aqueous Solution By UV Irradiation In The Presence Of Titanium Dioxide. Appl. Catal. B: Environ. 54: 85–91.

Yang, Y., Zhang, H., Wang, P., Zheng, Q., Li, J. 2007. The Influence Of Nano-Sized TiO2 Fillers On The Morphologies And Properties Of PSFUF Membrane. J. Membr Sci. 288: 231–238.

Davide Vionea, Claudio Mineroa, Valter Maurinoa, M. Eugenia Carlottib, Tatiana Picatonottoa, Ezio Pelizzettia. 2005. Degradation Of Phenol And Benzoic Acid In The Presence Of A TiO2-based Heterogeneous Photocatalyst. Applied Catalysis B: Environmental. 58: 79–88.

Gonu, Kim, Wonyong, Choi. 2010. Charge-Transfer Surface Complex Of EDTA-TiO2 And Its Effect On Photocatalysis Under Visible Light. Appl. Catal. B. 100: 77–83.

Seree, Tuprakay, Winai, Liengcharensit. 2005. Lifetime And Regeneration Of Immobilized Titania For Photocatalytic Removal Of Aqueous Hexavalent Chromium. Journal of Hazardous Materials. 124: 53–58.

Yang, Y., Wang, P. 2006. Preparation And Characterizations Of A New PS/TiO2 Hybrid Membrane By Sol-Gel Process. Polymer. 47: 5671–5681. [22] Swetha, S., Singh, M. K., Minchitha, K. U., Balakrishna, R. G. 2012. Elucidation of Cell Killing Mechanism by Comparative Analysis of Photoreactions on Different Types of Bacteria. Journal of Photochemistry and Photobiology. 88: 414–422.

Teow, Y. H., A. L. Ahmaqd, J. K. Lim, B. S. Ooi. 2012. Preparation And Characterization Of PVDF/TiO2 Mixed Matrix Membrane Via In Situ Colloidal Precipitation Method. Desalination. 295: 61–69.

Jyothi, M. S., Vignesh Nayak, Mahesh Padaki, R. Geetha Balakrishna, A. F. Ismail. 2014. The Effect Of UV Irradiation On PSf/TiO2 Mixed Matrix Membrane For Chromium Rejection. Desalination. 354: 189–199.

Mahesh, Padaki, Arun, M. Isloor, Ganesh, Belawadi, Narayan, Prabhu. K. 2011. Preparation and Performance Study of Poly(Isobutylene-alt-maleic anhydride) [PIAM] and Polysulfone [PSf] Composite Membranes Before And After Alkali Treatment. Ind. Eng. Chem. Res. 6528–6534.

Yoshitake Masuda. 2011. Nanofabrication edited by. ISBN 978-953-307-912-7.

Mahesh, Padaki, Arun, M. Isloor. Pikul, Wanichapichart, Ahmad, Fauzi, Ismail. 2012. Preparation And Characterization Of Sulfonated Polysulfone And N-phthloyl Chitosan Blend Composite Cation Exchange Membrane For Desalination. Desalination. 298: 42–48.

Liu, P., Lin, H. X., Fu, X. Z. 1995. Preparation Of The Doped Tio2 Film Photocatalyst And Its Bactericidal Mechanism. Chin J Catal. 20(3): 327–328.

Sakai, N. Fukuda, K. Shibata, T. Ebina, Y. Takada, K. Sasaki, T. 2006. Photoinduced Hydrophilic Conversion Properties Of Titania Nanosheets. J. Phys. Chem. B. 110: 6198–6203.

Rahimpour, A., S. S. Madaemi, A. H. Taheri, Y. Mansourpanah. 2008. Coupling TiO2 Nanoparticles With UV Irradiation For Modification Of Polyethersulfone Ultrafiltration Membranes. J. Membr. Sci. 313: 158.

Bae, T. H., T. M. Tak. 2005. Effect of TiO2 Nanoparticles On Fouling Mitigation Of Ultra-Filtration Membranes For Activated Sludge Filtration. J. Membr. Sci. 240: 1–8.

Shifu, C. and L. Yunzhang. 2007. Study On The Photocatalytic Degradation Of Glyphosate By Tio2 Photocatalyst. Chemosphere. 67(5): 1010–1017.

Bahnemann, W., M. Muneer, and M. M. Haque. 2007. Titanium Dioxide-Mediated Photocatalysed Degradation Of Few Selected Organic Pollutants In Aqueous Suspensions. Catalysis Today. 124(3-4): 133–148.

Kazuo Ikeda, Sukeji Suzuki, Yohya Watanabe. 1990. Determination Of Sunscreen Agents In Cosmetic Products By Gas Chromatography And Gas Chromatography-Mass Spectrometry. Journal of Chromatography A. 513: 321–326.

Downloads

Published

2017-11-13

How to Cite

Babu, V. S., Jyothi, M. S., P. D’Souza, L., Shwetharani, R., Padaki, M., & Geetha Balakrishna, R. (2017). Elimination of an Endocrine Disruptive Chemical by PSf/TiO2 hybrid Membranes via Membrane Rejection and Photocatalytic Oxidation. Journal of Applied Membrane Science & Technology, 19(1). https://doi.org/10.11113/amst.v19i1.20

Issue

Section

Articles