Hydrophilicity Enhancement of Metal Oxide Nanoparticles Incorporated Polysulfone Ultrafiltration Membrane

Authors

  • N. S. M. Sabri Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • H. Hasbullah Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • N. Said Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • N. Ibrahim Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • R. M. Kasmani Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • R. R. Ali Malaysia-Japan International Institute of Technology, Universiti Teknologi Malaysia Kuala Lumpur, Jalan Sultan Yahya Petra, 54100 Kuala Lumpur, Wilayah Persekutuan Kuala Lumpur, Malaysia
  • S. A. Rahman Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuhraya Tun Razak, Kuantan, Malaysia

DOI:

https://doi.org/10.11113/amst.v20i1.26

Abstract

Hydrophilicity property of membrane is a crucial feature in preventing fouling by most organic components including proteins. In this work, two different metal oxide nanoparticles were selected and their effects on hydrophilicity of polysulfone (PSf) flat sheet membrane for ultrafiltration were investigated. Addition of copper oxide (CuO) and iron oxide (Fe2O3) of 0.25 wt% concentration in N-methyl-2-pyrrolidone (NMP) were also compared to a neat PSf membrane. The membranes were prepared via dry-wet phase inversion technique with 18 wt% of PSf with 5 wt% polyvinylpyrrolidone (PVP). The physical and chemical properties of the prepared membranes were observed by contact angle measurements, porosity, average pore size and scanning electron microscope (SEM). The membranes permeation performance was also examined in term of pure water flux (PWF) and protein rejection by using bovine serum albumin (BSA) solution. Contact angle value of CuO/PSf obtained was 67.1° that was lower than the neat PSf membrane of 87.9° whereas 68.1° for Fe2O3/PSf indicating that metal oxides addition did enhance the membrane hydrophilicity with CuO was slightly better than Fe2O3. The reduction in contact angle ensured that the pure water flux through the membrane with metal oxide additive would improve as well. For CuO, the PWF increased to 159.3 Lm-2hr-1 from 81.3 Lm-2hr-1 of neat PSf, while Fe2O3 showed the PWF at 93.4 Lm-2hr-1. Morphological analyses displayed asymmetric membranes with narrow finger-like structure were formed in this study. A well-formed dense top layer indicated that the membrane would possess good BSA rejection property with 92% of rejection achieved by CuO/PSf membrane. The incorporation of nanoparticles with the membrane is proven to be an effective mean to increase the membrane hydrophilicity with improved water flux and BSA rejection.

References

S. Shirazi, C. J. Lin, and D. Chen. 2010. Inorganic Fouling of Pressure-driven Membrane Processes-A Critical Review. Desalination. 250(1): 236–248.

N. Ali, H. Sofiah, A. Asmadi, and A. Endut. 2011. Preparation and Characterization of a Polysulfone Ultrafiltration Membrane for Bovine Serum Albumin Separation: Effect of Polymer Concentration. Desalin. Water Treat. 32(1–3): 248–255.

L. Huang, S. Zhao, Z. Wang, J. Wu, J. Wang, and S. Wang. 2016. In Situ Immobilization of Silver Nanoparticles for Improving Permeability, Antifouling and Anti-bacterial Properties of Ultrafiltration Membrane. J. Memb. Sci. 499: 269–281.

M. K. Sinha and M. K. Purkait. 2013. Increase in Hydrophilicity of Polysulfone Membrane Using Polyethylene Glycol Methyl Ether. J. Memb. Sci. 437: 7–16.

Z. Xu, S. Ye, F. Zheng, R. Fanghua, G. Congjie, L. Qingbiao, L. Guoqing, Z. Guoliang. 2015. Preparation of Cu2O Nanowire-blended Polysulfone Ultrafiltration Membrane with Improved Stability and Antimicrobial Activity. J. Nanoparticle Res. 17: 409: 10: 1–9.

A. Urkiaga, D. Iturbe, and J. Etxebarria. 2015. Effect of Different Additives on the Fabrication of Hydrophilic Polysulfone Ultrafiltration Membranes. Desalin. Water Treat. 56(13): 3415–3426.

C. Mbareck and Q. T. Nguyen, 2014. Study of Polysulfone and Polyacrylic Acid (PSF/PAA) Membranes Morphology by Kinetic Method and Scanning Electronic Microscopy. J Membra Sci Technol. 5(1): 1–7.

D. Y. Koseoglu-Imer, B. Kose, M. Altinbas, and I. Koyuncu. 2013. The Production of Polysulfone (PS) Membrane with Silver Nanoparticles (AgNP): Physical Properties, Filtration Performances, and Biofouling Resistances of Membranes. J. Memb. Sci. 428(1–3): 620–628.

N. A. A. Hamid, A. F. Ismail, T. Matsuura, A. W. Zularisam, W. J. Lau, E. Yuliwati, M. S. Abdullah. 2011. Morphological and Separation Performance Study of Polysulfone/Titanium Dioxide (PSF/TiO2) Ultrafiltration Membranes for Humic Acid Removal. Desalination. 273(1): 85–92.

T. D. Dipheko, K. P. Matabola, K. Kotlhao, R. M. Moutloali, and M. Klink. 2017. Fabrication and Assessment of ZnO Modified Polyethersulfone Membranes for Fouling Reduction of Bovine Serum Albumin. Int. J. Polym. Sci. 8.

H. Basri, A. F. Ismail, and M. Aziz. 2011. Polyethersulfone (PES)–silver Composite UF Membrane : Effect of Silver Loading and PVP Molecular Weight on Membrane Morphology and Antibacterial Activity. Desalination. 273(1): 72–80.

N. Akar, B. Asar, N. Dizge, and I. Koyuncu. 2013. Investigation of Characterization and Biofouling Properties of PES membrane Containing Selenium and Copper Nanoparticles. J. Memb. Sci. 437: 216–226.

M. Homayoonfal, M. Reza, M. Shariaty-niassar, and A. Akbari. 2014. A Comparison Between Blending and Surface Deposition Methods for the Preparation of Iron Oxide/Polysulfone Nanocomposite Membranes. Desalination. 354: 125–142.

A. S. Al-Hobaib, K. M. Al-Sheetan, M. R. Shaik, N. M. Al-Andis, and M. S. Al-Suhybani. 2015. Characterization and Evaluation of Reverse Osmosis Membranes Modified with Ag2O Nanoparticles to Improve Performance. Nanoscale Res. Lett. 10(1): 379.

A. Sotto, J. Kim, J. M. Arsuaga, G. del Rosario, A. Martínez, D. Nam, P. Luis, B. Van der Bruggen. 2014. Binary Metal Oxides for Composite Ultrafiltration Membranes. J. Mater. Chem. A. 2(19): 7054–7064.

M. O. Mavukkandy, M. R. Bilad, A. Giwa, S. W. Hasan, and H. A. Arafat 2016. Leaching of PVP from PVDF/PVP Blend Membranes: Impacts on Membrane structure and Fouling in Membrane Bioreactors. J. Mater. Sci. 51(9): 4328–4341.

S. R. Panda and S. De. 2013. Role of Polyethylene Glycol with Different Solvents for Tailor-made Polysulfone Membranes. J. Polym. Res. 20(7): 16.

M. Z. Yunos, Z. Harun, H. Basri, A. F. Ismail, and D. Wang. 2012. Effects of Water as Non-Solvent Additive on Performance of Polysulfone Ultrafiltration Membrane. Adv. Mater. Res. 488–489: 46–50.

J. Alam, L. A. Dass, M. Ghasemi, and M. Alhoshan. 2013. Synthesis and Optimization of PES-Fe3O4 Mixed Matrix Nanocomposite Membrane : Application Studies in Water Purification. Polym. Compos. 34(11): 1–8.

P. T. P. Aryanti, S. R. Joscarita, A. K. Wardani, S. Subagjo, D. Ariono, and I. G. Wenten. 2015. The Influence of PEG400 and Acetone on Polysulfone Membrane Morphology and Fouling Behaviour. J. Eng. Technol. Sci. 48(2): 173–182.

Downloads

Published

2017-11-14

How to Cite

Sabri, N. S. M., Hasbullah, H., Said, N., Ibrahim, N., Kasmani, R. M., R. Ali, R., & Rahman, S. A. (2017). Hydrophilicity Enhancement of Metal Oxide Nanoparticles Incorporated Polysulfone Ultrafiltration Membrane. Journal of Applied Membrane Science &Amp; Technology, 20(1). https://doi.org/10.11113/amst.v20i1.26

Issue

Section

Articles