Electrospun Bi-layered Composite Membrane for the Removal of Metallic Contaminants in Drinking Water
DOI:
https://doi.org/10.11113/amst.v23n3.171Abstract
Using biodegradable polymer polycaprolactone (PCL) and zeolite, the present experiment was conducted with the aim of using biodegradable PCL and zeolite based composite membrane to remove silver in drinking water. After optimizing the electrospinning parameters, a double-layered PCL and PCL/zeolite electrospun composite membranes were manufactured. The membranes were then characterized using a scanning electron microscope (SEM) and an energy dispersive X-ray (EDX) and the filtration phenomenon was conducted by dispersing silver nanoparticles in water. After comparing the filtration results using an inductively coupled plasma optical emission spectrometry (ICP-OES), it was observed that the bi-layered membrane filtered 90% of silver present in the water. The present work shows that the new PCL/zeolite based double-layered membrane can be promising to remove contaminants in drinking water.
References
J. O. Duruibe, M. O. C. Ogwuegbu, and J. N. Egwurugwu. 2007. Heavy Metal Pollution and Human Biotoxic Effects. Int. J. Physic. Sci. 2(5): 112-118.
S. C. Bondy. 2010. The Neurotoxicity of Environmental Aluminum is Still an Issue. Neurotoxicology. 31(5): 575-581.
S. Brenner. 2013. Aluminum May Mediate Alzheimer's Disease through Liver Toxicity, with an Aberrant Hepatic Synthesis of Ceruloplasmin and Atpase7b, the Resultant Excess Free Copper Causing Brain Oxidation, Beta-amyloid Aggregation and Alzheimer Disease. Medic. Hypoth. 80(3): 326.
A. Pineau, B. Fauconneau, A. P. Sappino, R. Deloncle, and O. Guillard. 2014. If Exposure to Aluminium in Antiperspirants Presents Health Risks, Its Content Should Be Reduced. J. Trace Elem. Med. Biol. 28(2): 147-150.
P. D. Darbre. 2016. Aluminium and the Human Breast. Morphologie. 100(329): 65-74
L. Farzin, M. Amiri, H. Shams, M. A. A. Faghih, M. E. Moassesi. 2008. Blood Levels of Lead, Cadmium, and Mercury in Residents of Tehran. Biolog. Tra. Elem. Res. 123(1-3): 14-26.
L. R. Rosa, R. D. Rosa, M. A. M. S. da Veiga. 2016. Colloidal Silver and Silver Nanoparticles Bioaccessibility in Drinking Water Filters. J. Env. Chem. Eng. 4(3): 3451-3458.
K. M. Stepien, R. Morris, S. Brown, A. Taylor, L. Morgan. 2009. Unintentional Silver Intoxication Following Self-medication: An Unusual Case of Corticobasal Degeneration. Annals Clinic. Biochem. 46(6): 520-522.
M. C. Stensberg, Q. Wei, E. S. McLamore, D. M. Porterfield, A. Wei, M. S. Sepúlveda. 2011. Toxicological Studies on Silver Nanoparticles: Challenges and Opportunities in Assessment, Monitoring, and Imaging. Nanomedicine. 6(5): 879-898.
N. Cruz, S. M. Rodrigues, D. Tavares, R. J. R. Monteiro, L. Carvalho, T. Trindade, A. C. Duarte, E. Pereira, E., P. F. Römkens. 2015. Testing Single Extraction Methods and in Vitro Tests to Assess the Geochemical Reactivity and Human Bioaccessibility of Silver in Urban Soils Amended with Silver Nanoparticles. Chemosphere. 135: 304-311.
N. Sultana, T. H. Khan. 2013. Polycaprolactone Scaffolds and Hydroxyapatite/Polycaprolactone Composite Scaffolds for Bone Tissue Engineering. J. Bionanosci.7(2): 169-173.
J. Song, H. Gao, G. Zhu, X. Cao, X. Shi, Y. Wang. 2015. The Preparation and Characterization of Polycaprolactone/Graphene Oxide Biocomposite Nanofiber Scaffolds and Their Application for Directing Cell Behaviors. Carbon. 95: 1039-1050.
M. M. Lim. 2013. Electrospun Membranes for Drug Delivery and Tissue Engineering Applications. Doctoral Dissertation. Universiti Teknologi Malaysia.
V. P. Mallapur, J. U. K. Oubagaranadin, S. S. Lature. 2013. Synthesis of Zeolite from Inorgranic Wastes. IJRET. 431-433.
R. Balamurugan, S. Sundarrajan, S. Ramakrishna. 2011. Recent Trends in Nanofibrous Membranes and Their Suitability for Air and Water Filtrations. Membranes. 1(3): 232-248.
M. I. Hassan, T. Sun, N. Sultana. 2014. Fabrication of Nanohydroxyapatite/poly (caprolactone) Composite Microfibers Using Electrospinning Technique for Tissue Engineering Applications. J. Nanomater. 2014: 1-10.
S. Wanjale, M. Birajdar, J. Jog, R. Neppalli, V. Causin, J. Karger-Kocsis, J. Lee, P. Panzade. 2016. Surface Tailored PS/TiO 2 Composite Nanofiber Membrane for Copper Removal from Water. J. Colloid Interf. Sci. 469: 31-37.
S. A. A. N. Nasreen, S. Sundarrajan, S. A. S. Nizar, R. Balamurugan, S. Ramakrishna. 2013. Advancement in Electrospun Nanofibrous Membranes Modification and Their Application in Water Treatment. Membranes. 3(4): 266-284.
S. Nagamine, T. Matsumoto, Y. Hikima, M. Ohshima. 2016, Fabrication of Porous Carbon Nanofibers by Phosphate-Assisted Carbonization of Electrospun Poly (Vinyl Alcohol) Nanofibers. Mater. Res. Bulletin. 79: 8-13.
A. Huang, H. Bux, F. Steinbach, J. Caro. 2010, Molecularâ€sieve Membrane with Hydrogen Permselectivity: ZIFâ€22 in LTA Topology Prepared with 3â€Aminopropyltriethoxysilane as a Covalent Linker. Angewandte Chemie. 122(29): 5078-508.
V. Pillay, C. Dott, Y. E. Choonara, C. Tyagi, L. Tomar, P. Kumar, L. C. du Toit, V. M. Ndesendo. 2013. A Review of the Effect of Processing Variables on the Fabrication of Electrospun Nanofibers for Drug Delivery Applications. J. Nanomater. 2013: 1-10.
K. Margeta, A. Farkas, M. Å iljeg, N. Z. Logar. 2013. Natural Zeolites in Water Treatment-How Effective is Their Use. Intech Open Access Publisher. 81-106.
M. Makaremi, C. X. Lim, P. Pasbakhsh, S. M. Lee, K. L. Goh, H. Chang. 2016. Electrospun Functionalized Polyacrylonitrile–chitosan Bi-layer Membranes for Water Filtration Applications. RSC Adv. 6: 53882-53893.
V. Sencadas, D. M. Correia, C. Ribeiro, S. Moreira, G. Botelho, J. G. Ribelles. 2012. Physical-chemical Properties of Cross-linked Chitosan Electrospun Fiber Mats. Polym. Test. 31: 1062-1069.
K. Govindasamy, C. Fernandopulle, P. Pasbakhsh, and K. Goh. 2014. Synthesis and Characterisation of Electrospun Chitosan Membranes Reinforced by Halloysite Nanotubes. J. Mecha. Med. Biol. 14: 1450058.
Downloads
Published
How to Cite
Issue
Section
License
Copyright of articles that appear in Journal of Applied Membrane Science & Technology belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.