Fabrication and Characterization of Polysulfone-Zeolite ZSM-5 Mixed Matrix Membrane for Heavy Metal Ion Removal Application

Authors

  • G. P. Syed Ibrahim Membrane Technology Laboratory, Department of Chemistry, National Institute of Technology Karnataka, Surathkal, Mangalore 575 025, India
  • Arun M. Isloor Membrane Technology Laboratory, Department of Chemistry, National Institute of Technology Karnataka, Surathkal, Mangalore 575 025, India
  • Amir Al Ahmed Center of Research Excellence in Renewable Energy (CORE-RE), King Fahd University of Petroleum & Minerals, Saudi Arabia
  • B. Lakshmi Department of Chemistry, Reva University, Bangalore 560054, Karnataka, India

DOI:

https://doi.org/10.11113/amst.v18i1.17

Abstract

Mixed matrix membranes (MMMs) of Polysulfone (PSf)-Zeolite ZSM-5 (ZZSM-5) were prepared by phase inversion method with a dose ranging from 1.0 to 4.0 Wt. % with polyvinylpyrrolidone (PVP) as the fore forming agent. The prepared mixed matrix membranes were scrutinized for their permeation, hydrophilicity and anti-fouling nature. Characterization of the membrane was carried out by Electrokinetic analyzer. The heavy metal ions rejection experiment has been carried out and the results manifested that, the PZM-4 membrane exhibits higher pure water flux of 348.88 L/m2 h, contact angle of 72.7o and the heavy meals rejection of Pb2+ (98.54%) and of Cd2+ (95.32%) ions. Taken as a whole, the modified PSf-ZZSM-5 ultrafiltration membranes are the attractive candidate for the water treatment.

References

M. A. Shannon, P. W. Bohn, M. Elimelech, J. G. Georgiadis, B. J. Marinas and A. M. Mayes. 2008. Science And Technology For Water Purification In The Coming Decades. Nature. 452: 301–310.

H. W. Liang, X. Cao, W. J. Zhang, H. T. Lin, F. Zhou, L. F. Chen and S. H. Yu. 2011. Robust and Highly Efficient Free-Standing Carbonaceous Nanofiber Membranes for Water Purification. Adv. Funct. Mater. 21: 3851–3858.

J. Yin and B. Deng. 2015. Polymer-Matrix Nanocomposite Membranes For Water Treatment. J. Membr. Sci. 479: 256–275.

Anna Lee, Jeffrey W. Elamb and Seth B. 2016. Darling, Membrane Materials For Water Purification: Design, Development, And Application Environ. Sci. Water Res.Technol. 2: 17–42.

N. C. van de Merbel, J. J. Hageman, U.A. Th. Brinkman. 1993. Membrane-based Sample Preparation For Chromatography. J. Chromatogr. 634: 1–29.

Valeen Rashmi Pereira, Arun M. Isloor, Udaya K. Bhat, A. F. Ismail, Abdulrahman Obaid and Hoong-Kun Fun. 2015. Preparation And Performance Studies Of Polysulfone-Sulfated Nano-Titania (S-Tio2) Nanofiltration Membranes For Dye Removal. RSC Adv. 5: 53874.

B. M. Ganesh, Arun M. Isloor, A. F. Ismail. 2013. Enhanced Hydrophilicity And Salt Rejection Study Of Graphene Oxide-Polysulfone Mixed Matrix Membrane. Desalination. 313: 199–207.

Raghavendra S. Hebbar, Arun M. Isloor, K. Anandab and A. F. Ismail. 2016. Fabrication Of Polydopamine Functionalized Halloysite Nanotube/Polyetherimide Membranes For Heavy Metal Removal. J. Mater. Chem. A. 4: 764–774.

Hyun Gyu Park, Tae Won Kim, Myeong Yun Chae, Ik-Keun Yoo. 2007. Activated Carbon Containing Alginate Adsorbent For The Simultaneous Removal Of Heavy Metals And Toxic Organics. Process Biochemistry. 42: 1371–1377.

N. Abdullah, R. J. Gohari, N. Yusof, A. F. Ismail, J. Juhana, W. J. Lau, T. Matsuura. 2016. Polysulfone/Hydrous Ferric Oxide Ultrafiltration Mixed Matrix Membrane: Preparation, Characterization And Its Adsorptive Removal Of Lead (II) From Aqueous Solution. Chemical Engineering Journal. 289: 28–37.

E. Ayranci, O. Duman. 2004. Binding Of Lead Ion On Bovine Serum Albumin Studies By Ion Selective Electrode. Protein Pept. Lett. 11: 331–337.

R. Jamshidi Gohari, W. J. Lau, T. Matsuura, E. Halakoo, A. F. Ismail. 2013. Adsorptive Removal Of Pb (II) From Aqueous Solution By Novel PES/HMO Ultrafiltration Mixed Matrix Membrane. Sep. Purif. Technol. 120: 59–68.

B.Volesky. 2007.Biosorption And Me. Water Res. 41: 4017–4029.

T. Theophanides, J. 2002. Anastassopoulou, Copper and Carcinogenesis. Crit. Rev. Oncol. Haematol. 42: 57–64.

Xiaoqin Zou, Guangshan Zhu, Hailing Guo, Xiaofei Jing, Diou Xu, Shilun Qiu. 2009. Effective Heavy Metal Removal Through Porous Stainless- Steel-Net Supported Low Siliceous Zeolite ZSM-5 Membrane. Microporous and Mesoporous Materials. 124: 70–75.

M. Mulder. 1996. Basic Principles of Membrane Technology. Second edition. Kluwer Academic Publishers.

Dong, Y. Y. Xu, Z. Yi, J. L. Shi. 2009. Modification Of Polysulfone Membranes Via Surface-Initiated Atom Transfer Radical Polymerization. Appl.Surf.Sci. 255: 8860–8866.

Raghavendra S. Hebbar, Arun M. Isloor, A. F. Ismail, Simon J. Shilton, Abdulrahman Obaid and Hoong-Kun Fun. 2015. Probing The Morphology And Anti-Organic Fouling Behavior Of A Polyetherimide Membrane Modified With Hydrophilic Organic Acids As Additives. New J. Chem. 39: 6141–6150. [19] Rajesha Kumar, Arun M. Isloor, A. F. Ismail, T. Matsuura. 2013. Performance Improvement Of Polysulfone Ultrafiltration Membrane Using N-Succinyl Chitosan As Additive. Desalination. 318: 1–8. [20] Irfana Moideen K, Arun M. Isloor, A. F. Ismail, Abdulrahman Obai Hoong-Kun Fun. 2015. Fabrication And Characterization Of New PSF/PPSU UF Blend Membrane For Heavy Metal Rejection. Desalination and Water Treatment. 1–10.

Urkiaga, A, Iturbe, D, Etxebarria, J. 2015. Effect Of Different Additives On The Fabrication Of Hydrophilic Polysulfone Ultrafiltration Membranes. Desalination and Water Treatment. 56(13): 3415–3426

Sinha, M. K, Purkait, M. K. 2014. Preparation And Characterization Of Stimuli-Responsive Hydrophilic Polysulfone Membrane Modified With Poly (N-Vinylcaprolactam-Co-Acrylic Acid). Desalination. 348(1): 16–25.

Yurekli, Y. 2016. Removal Of Heavy Metals In Wastewater By Using Zeolite Nano-Particles Impregnated Polysulfone Membranes. Journal of Hazardous Materials. 309: 53–64.

Dong, L.-X, Yang, H.-W, Liu, S.-T,Wang, X.-M, Xie, Y. F. 2015. Fabrication And Anti-Biofouling Properties Of Alumina And Zeolite Nanoparticle Embedded Ultrafiltration Membranes. Desalination. 365: 70–78.

Liu, F, Ma, B.-R, Zhou, D, Xiang, Y.-H, Xue, L.-X. 2014. Breaking Through Tradeoff Of Polysulfone Ultrafiltration Membranes By Zeolite 4A. Microporous and Mesoporous Materials. 186: 113–120.

R. Kumar, A.M. Isloor, A. Ismail, S. A. Rashid, T. Matsuura. 2013. Polysulfone-Chitosan Blend Ultrafiltration Membranes: Preparation, Characterization, Permeation And Antifouling Properties. RSC Adv. 3: 7855–7861. [27] AndriyYaroshchuk and Thomas Luxbacher. 2010. Interpretation of Electrokinetic Measurements with Porous Films: Role of Electric Conductance and Streaming Current within Porous structure. Langmuir. 26(13): 10882–10889.

Song Zhaoa, Zhi Wanga, Xin Wei, Boran Zhaoa, Jixiao Wanga, Shangbao Yanga, Shichang Wang. 2011. Performance Improvement Of Polysulfone Ultrafiltration Membrane Using Panieb As Both Pore Forming Agent And Hydrophilic Modifier. Journal of Membrane Science. 385–386: 251–262.

Yaozu Liao, Thomas P. Farrell, Gregory R. Guillen, Minghua Li, James A. T. Temple, Xin-Gui Li, Eric M. V. Hoek and Richard B. Kaner. 2014. Highly Dispersible Polypyrrole Nanospheres For Advanced Nanocomposite Ultrafiltration Membranes. Mater. Horiz. 1: 58.

D. Rana, T. Matsuura. 2010. Surface Modifications for Antifouling Membranes, Chem. Rev. 110: 2448–2471. [31] Kimura K, Hane Y, Watanabe Y, Amy G, Ohkuma N. 2004. Irreversible Membrane Fouling During Ultrafiltration Of Surface Water. Water Res. 38: 3431–41.

V. Vatanpour, S. S. Madaeni, R. Moradian, S. Zinadini and B.

Astinchap. 2011. Fabrication And Characterization Of Novel Antifouling Nanofiltration Membrane Prepared From Oxidized Multiwalled Carbon Nanotube/Polyethersulfone Nanocomposite. J. Membr. Sci. 375: 284–294.

H. Zhao, L. Wu, Z. Zhou, L. Zhang and H. Chen. 2013. Improving The Antifouling Property Of Polysulfone Ultrafiltration Membrane By Incorporation Of Isocyanate-Treated Graphene Oxide, Phys. Chem.Chem. Phys. 15: 9084–9092.

M. Sun, Y. Su, C. Mu and Z. Jiang. 2009. Improved Antifouling Property of PES Ultrafiltration Membranes Using Additive of Silica−PVP Nanocomposite, Ind. Eng. Chem. Res. 49: 790–796.

A. Sotto, A. Boromand, S. Balta, J. Kim and B. van der Bruggen. 2011. Doping Of Polyethersulfone Nanofiltration Membranes: Antifouling Effect Observed At Ultralow Concentrations Of TiO2 Nanoparticles. J. Mater. Chem. 21: 10311–10320.

Downloads

Published

2017-11-13

How to Cite

Syed Ibrahim, G. P., M. Isloor, A., Al Ahmed, A., & Lakshmi, B. (2017). Fabrication and Characterization of Polysulfone-Zeolite ZSM-5 Mixed Matrix Membrane for Heavy Metal Ion Removal Application. Journal of Applied Membrane Science & Technology, 18(1). https://doi.org/10.11113/amst.v18i1.17

Issue

Section

Articles